Mary, Mary, How does your dewpoint vary?

Today we are modifying the old nursery rhyme which inquires about Mary's garden  to consider typical fluctuations in dewpoint temperature.  Since the dewpoint depends on the total atmospheric pressure, and that changes from day-to-day, the dewpoint will change (for a given amount of moisture in the air) as the barometric pressure changes. We'll also look at how dewpoint might change with altitude.

Water from Air

We’ve talked in other posts about how water will condense out of air when it is cooled past the dewpoint temperature.  So I got to wondering how much it would cost to produce water that way.  In this post we’ll look at a very rough estimate of the minimum cost.

Water in the Exhaust, Part 2

     In the last post we examined the water vapor that is present after the combustion of hydrocarbon fuels.  This time let’s look a little closer at the effects of excess air and water vapor in the combustion air on the amount of water vapor in the exhaust.

Water in the Exhaust

     Have you ever noticed white clouds of exhaust billowing out of a car’s tailpipe on a cold day? When hydrocarbon fuels (like gasoline, diesel fuel, oil, propane, natural gas, etc.) are burned in air, normally the vast majority of the exhaust consists of carbon dioxide, water vapor, and nitrogen.  All three of these gases are colorless and transparent, so when you see white exhaust coming out of a car or see an airplane’s contrail, it is light reflecting off the surfaces of tiny droplets of liquid water that have condensed from the water vapor.  In this post we’ll examine the amount of water produced by combustion, and the conditions under which it condenses.

Evaporative Cooling

Last post we talked about the psychrometric chart and the process that moist air follows on the chart when it is cooled until condensation begins.  You may be familiar with cooling systems that are variously termed “evaporative coolers”, “swamp coolers”, “desert coolers” and other names.  These systems work on something sort of like the inverse of the condensation process that we talked about last time.  Instead of cooling the moist air until liquid water condenses out, these systems evaporate liquid water into the air in order to cool it. 

Condensation from the Atmosphere

Have you ever noticed the beads of water that form on a cold beverage container in warm humid weather?  Or been annoyed by the fog that obscures your bathroom mirror when you are ready to shave or apply makeup?  Or seen white clouds billowing out of the tailpipe of a car on a cold day? These are all examples of water vapor in the air condensing into a liquid.  In the first two cases, the liquid condensation had formed on a cool surface, but condensation also occurs any time that you can see clouds, fog, or steam, as in the third case.  Water vapor is colorless and transparent, so when you can see a cloud, it is visible because of light reflecting off of tiny droplets of liquid.  In other words, condensation has already occurred by the time that you can see anything.

An Alternate View of Condensation

Usually when we think of condensation, we think of the droplets of water that form on a cold glass on a humid day, or perhaps we think of dew making the grass wet on a summer morning, or maybe the fog that forms on the bathroom mirror after you have a hot shower.  In those familiar cases of condensation, the water vapor is mixed in with dry air in a very dilute mixture.  For example, at 75 deg F, 60% relative humidity, the water vapor comprises only about 1.1% of the total moist air, by mass.  Even at 75 deg F, 100% relative humidity, (at which point the vapor is about to start condensing to liquid) the water vapor is only about 1.8% of the mixture.  So, we’re accustomed to condensation of water from a very dilute mixture of water vapor in air.  In this blog, we’ll consider the condensation of pure water vapor, and see some surprising forces.